Metal nanoparticles have long been considered to exhibit unique physical and chemical properties different from those of the bulk state or atoms due to the quantum size effect, resulting in specific electronic structures. These properties can be controlled not only by varying material composition but also by tuning size and shape of nanoparticles. Among metal nanoparticles, gold nanoparticles probably have the most attracted considerable interest and can be utilized in numerous applications ranging from catalyst, sensing, and self-assembly. We have developed facile and simple synthetic strategies for creating monodispersed gold nanoparticles in high yield with fine control over their shape and size mainly using a seedless method.
Synthesis of functionalized Single-Walled Carbon Nanotubes
Single-Walled Carbon nanotube (SWNT) is a promising material for nanoscale applications. To utilize it in a useful way, SWNT should be individually isolated in solution, which is, however, inhibited by intrinsic properties of SWNT. To achieve this, we functionalized SWNT in aqueous solution by adding polymerizable surfactant, leading to non-covalent functionalization. SWNT superstructure with well-defined morphology, density, and direction is also demanded to enhance their physical properties. Amphiphilic molecule is known to exhibit rich phase behavior and has been extensively used as a template for various nanostructured material. We have created various types of superstructures by mixing SWNT with amphiphilic molecules.